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This thesis describes the use of 2 mercaptobenzothiazole (MBT) as an auxiliary in organic chemistry for the preparation of alkenes, alkynes and allylated compounds. The transformations are based on the nucleophilic substitution of MBT to various electron deficient substrates and then oxidation to generate the key intermediates, benzothiazol christian louboutin outlet uk 2 yl sulfones (BT sulfones). Depending on the employed reaction conditions, BT sulfones underwent Smiles rearrangements through ...